Crystal structures of the Lewis acid-base adducts {[(C₆H₁₁)₂N]₃Ti-LB}⁺[MeB(C₆F₅)₃]^-·1.5C₇H₈; LB = (C₆H₅)₃PO (1), p-F-C₆H₄CN (2).

ABSTRACT: The reaction of [(C₆H₁₁)₂N]₃Ti-CH₃ with the Lewis acid B(C₆F₅)₃, followed by addition of the Lewis bases (C₆H₅)₃PO and p-F-C₆H₄CN led to the complex salts tris-(di-cyclo-hexyl-amido)(tri-phenyl-phosphine oxide)titanium methyl-tris(penta-fluoro-phen-yl)borate toluene sesquisolvate, [Ti(C₁₂H₂₂N)₃(C₁₈H₁₅OP)](C₁₉H₃F₁₅B)·1.5C₇H₈, (1), and tris-(di-cyclo-hexyl-amido)(4-fluoro-benzo-nitrile)-titanium methyl-tris-(penta-fluoro-phen-yl)borate toluene sesquisolvate, [Ti(C₁₂H₂₂N)₃(C₇H₄

SUBMITTER: Fitschen K 

PROVIDER: S-EPMC9443798 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature