Structure of water-in-salt and water-in-bisalt electrolytes.

ABSTRACT: We report a systematic diffraction study of two "water-in-salt" electrolytes and a "water-in-bisalt" electrolyte combining high-energy X-ray diffraction (HEXRD) with polarized and unpolarized neutron diffraction (ND) on both H₂O and D₂O solutions. The measurements provide three independent combinations of correlations between the different pairs of atom types that reveal the short- and intermediate-range order in considerable detail. The ND interference functions show pronounced peaks around a scattering vector Q ∼ 0.5 Å^-1 that change dramatically with composition, indicating significant rearrangements of the water network on a length scale around 12 Å. The experimental results are compared with two sets of Molecular Dynamics (MD) simulations, one in

SUBMITTER: Gonzalez MA 

PROVIDER: S-EPMC9445817 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature