Parallel triplet formation pathways in a singlet fission material.

ABSTRACT: Harvesting long-lived free triplets in high yields by utilizing organic singlet fission materials can be the cornerstone for increasing photovoltaic efficiencies potentially. However, except for polyacenes, which are the most studied systems in the singlet fission field, spin-entangled correlated triplet pairs and free triplets born through singlet fission are relatively poorly characterized. By utilizing transient absorption and photoluminescence spectroscopy in supramolecular aggregate thin films consisting of Hamilton-receptor-substituted diketopyrrolopyrrole derivatives, we show that photoexcitation gives rise to the formation of spin-0 correlated triplet pair ¹(TT) from the lower Frenkel exciton state. The existence of ¹(TT) is proved through faint Herzberg-Telle

SUBMITTER: Maity N 

PROVIDER: S-EPMC9448805 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature