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Au modified PrFeO₃ with hollow tubular structure can be efficient sensing material for H₂S detection.

ABSTRACT: The H₂S concentration in exhaled breath increases marginally with the progress of periodontal disease, and H₂S is considered to be one of the most important gases related to meat and seafood decomposition; however, the concentration of H₂S is low and difficult to detect in such scenarios. In this study, Au-PrFeO₃ nanocrystalline powders with high specific surface areas and porosities were prepared using an electrospinning method. Our experimental results show that loading Au on the material provides an effective way to increase its gas sensitivity. Au doping can decrease the material's resistance by adjusting its energy band, allowing more oxygen ions to be adsorbed onto the material's surface due to a spillover effect. Compared with pure PrFeO₃, the response of 3 wt% Au-PrFeO₃ is improved by more than 10 times, and the response time is more than 10 s shorter. In addition, the concentration of H₂S due to the decomposition of shrimp was detected using the designed gas sensor, where the error was less than 15%, compared with that obtained using a GC-MS method. This study fully demonstrates the potential of Au-PrFeO₃ for H₂S concentration detection.

SUBMITTER: Zhang H

PROVIDER: S-EPMC9449130 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature

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Au modified PrFeO3 with hollow tubular structure can be efficient sensing material for H2S detection.

Zhang Heng H Xiao Jing J Chen Jun J Zhang Lian L Zhang Yi Y Jin Pan P

Frontiers in bioengineering and biotechnology 20220824

The H2S concentration in exhaled breath increases marginally with the progress of periodontal disease, and H2S is considered to be one of the most important gases related to meat and seafood decomposition; however, the concentration of H2S is low and difficult to detect in such scenarios. In this study, Au-PrFeO3 nanocrystalline powders with high specific surface areas and porosities were prepared using an electrospinning method. Our experimental resul ...[more]

PMID: 36091448

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Project description:ObjectiveAlthough photoelectrochemical (PEC) water splitting heralds the emergence of the hydrogen economy, the need for external bias and low efficiency stymies the widespread application of this technology. By coupling water splitting (in a PEC cell) to a microbial fuel cell (MFC) using Escherichia coli as the biocatalyst, this work aims to successfully demonstrate a sustainable hybrid PEC-MFC platform functioning solely by biocatalysis and solar energy, at zero bias. Through further chemical modification of the photo-anode (in the PEC cell) and biofilm (in the MFC), the performance of the hybrid system is expected to improve in terms of the photocurrent generated and hydrogen evolved.MethodsThe hybrid system constitutes the interconnected PEC cell with the MFC. Both PEC cell and MFC are typical two-chambered systems housing the anode and cathode. Au-TiO2 hollow spheres and conjugated oligoelectrolytes were synthesised chemically and introduced to the PEC cell and MFC, respectively. Hydrogen evolution measurements were performed in triplicates.ResultsThe hybrid PEC-MFC platform generated a photocurrent density of 0.35 mA/cm2 (~70× enhancement) as compared with the stand-alone P25 standard PEC cell (0.005 mA/cm2) under one-sun illumination (100 mW/cm2) at zero bias (0 V vs. Pt). This increase in photocurrent density was accompanied by continuous H2 production. No H2 was observed in the P25 standard PEC cell whereas H2 evolution rate was ~3.4 μmol/h in the hybrid system. The remarkable performance is attributed to the chemical modification of E. coli through the incorporation of novel conjugated oligoelectrolytes in the MFC as well as the lower recombination rate and higher photoabsorption capabilities in the Au-TiO2 hollow spheres electrode.ConclusionsThe combined strategy of photo-anode modification in PEC cells and chemically modified MFCs shows great promise for future exploitation of such synergistic effects between MFCs and semiconductor-based PEC water splitting.

Dataset Information

Au modified PrFeO₃ with hollow tubular structure can be efficient sensing material for H₂S detection.

Publications

Au modified PrFeO<sub>3</sub> with hollow tubular structure can be efficient sensing material for H<sub>2</sub>S detection.

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