A Rearrangement Reaction to Yield a NH₄ ⁺ Ion Driven by Polyoxometalate Formation.

ABSTRACT: Triethylamine is a volatile liquid and exists in the atmosphere in the gas phase. It is a hazardous air pollutant and identified as a toxic air contaminant. Thus, producing ammonia (a vital chemical for fertilizer production) from the vapor state of this toxic substance is a challenging task. Diffusion of the vapor of triethylamine, (C₂H₅)₃N, into an acidified aqueous solution of sodium molybdate results in the formation of single crystals of compound [(C₂H₅)₃NH]₂[(C₂H₅)₄N][NaMo₈O₂₆] (1). Notably, compound 1 includes a [(C₂H₅)₄N]⁺ cation, even though the concerned reaction mixture was not treated with a

SUBMITTER: Kumar NT 

PROVIDER: S-EPMC9454273 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature