Crystal Engineering and Photomagnetic Studies of CN-Bridged Coordination Polymers Based on Octacyanidometallates(IV) and [Ni(cyclam)]².

ABSTRACT: A series of new CN-bridged coordination networks of different dimensionality and topology was obtained through the modification of reaction conditions between [Ni(cyclam)]²⁺ (cyclam = 1,4,8,11-tetraazacyclotetradecane) and [W(CN)₈]^4-. The factors determining the reaction pathway are temperature and addition of the LiCl electrolyte. The products include three negatively charged frameworks incorporating Li⁺ guests: the 1D Li₂[Ni(cyclam)][W(CN)₈]·6H₂O (1) straight chain, the 1D Li₂[Ni(cyclam)][W(CN)₈]·2H₂O (2) zigzag chain, and the 2D Li₂[Ni(cyclam)]₃[W(CN)₈]₂·24H₂O (3) honeycomb-like network, as well as the 3

SUBMITTER: Heczko M 

PROVIDER: S-EPMC9455600 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature