Polar Layered Intermetallic LaCo₂P₂ as a Water Oxidation Electrocatalyst.

ABSTRACT: We investigate LaCo₂P₂ as an electrocatalytic material for oxygen evolution reaction (OER) under alkaline and acidic conditions. This layered intermetallic material was prepared via Sn-flux high-temperature annealing. The electrocatalytic ink, prepared with the ball-milled LaCo₂P₂ catalyst at the mass loading of 0.25 mg/cm², shows OER activity at pH = 14, reaching current densities of 10, 50, and 100 mA/cm² under the overpotential of 400, 440, and 460 mV, respectively. Remarkably, the electrocatalytic performance remains constant for at least 4 days. Transmission electron microscopy reveals the formation of a catalytically active CoO_x shell around the pre-catalyst LaCo₂P₂ core d

SUBMITTER: Mann DK 

PROVIDER: S-EPMC9455929 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature