Covalent Organic Frameworks-TpPa-1 as an Emerging Platform for Electrochemical Sensing.

ABSTRACT: Covalent organic frameworks (COFs) are a new type of metal-free porous architecture with a well-designed pore structure and high stability. Here an efficient electrochemical sensing platform was demonstrated based on COFs TpPa-1 constructed by 1,3,5-triformylphloroglucinol (Tp) with p-phenylenediamine (Pa-1), which possesses abundant nitrogen and oxo-functionalities. COFs TpPa-1 exhibited good water dispersibility and strong adsorption affinities for Pd²⁺ and thus was used as loading support to modify Pd²⁺. The Pd²⁺-modified COFs TpPa-1 electrode (Pd²⁺/COFs) showed high electrocatalytic activity for both hydrazine oxidation reaction and nitrophenol reduction reaction. In addition, TpPa-1-derived nitrogen-doped carbon presented high activity for t

SUBMITTER: Li G 

PROVIDER: S-EPMC9457582 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature