trans-Bis(4-amino-pyridine-κN)bis-(quin-ox-aline-2,3-di-thiol-ato-κ² S,S')platinum(IV) dimethyl sulfoxide monosolvate.

ABSTRACT: In the structure of the title solvated complex, [Pt(C₈H₄N₂S₂)₂(C₅H₆N₂)₂]·C₂H₆OS or trans-[Pt(4-ap)₂(qdt)₂]·dmso (4-ap = 4-amino-pyridyl, C₅H₆N₂; qdt = quinoxaline-2,3-di-thiol-ate, C₈H₄N₂S₂; dmso = dimethyl sulfoxide, C₂H₆OS) the centrosymmetric complex exhibits Pt-S distances in agreement with other Pt^IV-S bond lengths found in platinum(IV) di-thiol-ene complexes. The qdt ligands have inter-molecular inter-actions with an amine hydrogen atom on a 4-ap ligand (hydrogen bonding) and have sandwich π-π inter-actions

SUBMITTER: Hu J 

PROVIDER: S-EPMC9462004 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature