([2.2.2]Cryptand)potassium (4-methyl­benzene­thiol­ato)[5,10,15,20-tetra­kis­(4-chloro­phen­yl)porphyr­inato]manganate(II) tetra­hydro­furan disolvate

ABSTRACT: The MnII centre is coordinated by four pyrrole N atoms of the porphyrin ring and one S atom of the axial 4-methyl­benzene­thiol­ate ligand. Two tetra­hydro­furan mol­ecules and a potassium cation chelated inside a [2.2.2]cryptand (4,7,13,16,21,24-hexa­oxa-1,10-di­aza­bicyclo­[8.8.8]hexa­cosa­ne) are also present. Single crystals of the title compound, [K(C18H36N2O6)][Mn(C44H24Cl4N4)(C7H7S)]·2C4H8O, were obtained by the solvent evaporation method. The MnII cation is coordinated by four pyrrole N atoms (Np) of the porphyrin ring and one S atom of the apical 4-methyl­benzene­thiol­ate ligand with the average Mn—Np and the apical Mn—S bond lengths being 2.160 (9) and 2.4642 (8) Å, respectively. Two tetra­hydro­furan solvent mol­ecules and a potassium cation chelated inside a [2.2.2]cryptand (4

SUBMITTER: Yuan Y 

PROVIDER: S-EPMC9462021 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature