Poly[bis[μ2-4,4′-bis(imidazol-1-ylmethyl)biphenyl-κ2N:N′]dichloridonickel(II)]
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ABSTRACT: The crystal structure of a two-dimensional metal–organic compound constructed from 4,4′-bis[(1H-imidazol-1-yl)methyl]-1,1′-biphenyl (BIMB) and nickel ions is described. Each BIMB ligand adopts a linear linker to connect Ni2+ ions, forming a layer with an sql network. In the crystal, neighboring layers repeat in an ABAB stacking mode, and weak intermolecular C—H⋯Cl hydrogen bonds between alternate layers lead to a three-dimensional, twofold interpenetrated, supramolecular framework with a pcu topology net. In the title compound, [NiCl2(C20H18N4)2]n, the Ni2+ cation is situated on an inversion center and is coordinated by two chloride ions and four imidazole N atoms of four different 4,4′-bis[(1H-imidazol-1-yl)methyl]-1,1′-biphenyl (BIMB), forming a slightly distorted octahedral geom
SUBMITTER: Deng M
PROVIDER: S-EPMC9462028 | biostudies-literature | 2022 Apr
REPOSITORIES: biostudies-literature
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