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Bis(4-phenyl-2-sulfanyl-idene-2,3-di-hydro-1,3-thia-zol-3-ido-κ² S ²,N)(4-phenyl-1,3-thia-zole-2-thiol-ato-κS ²)bis-muth.

ABSTRACT: The title compound, [Bi(C₉H₆NS₂)₃], was prepared by reacting BiCl₃ and 2-mercapto-4-phenyl-thia-zole (LH) at room temperature in a stoichiometric ratio of 1:4. The mol-ecular structure reveals a slightly distorted square-pyramidal environment around the Bi^III atom. Two of the three monoanionic ligands L ^- coordinate in an N,S-bidentate mode, while one shows a monodentate mode through an S atom. There are no significant inter-molecular inter-actions present in the crystal.

SUBMITTER: Stammler HG

PROVIDER: S-EPMC9462144 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Dataset Information

Bis(4-phenyl-2-sulfanyl-idene-2,3-di-hydro-1,3-thia-zol-3-ido-κ² S ²,N)(4-phenyl-1,3-thia-zole-2-thiol-ato-κS ²)bis-muth.

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Bis(4-phenyl-2-sulfanyl-idene-2,3-di-hydro-1,3-thia-zol-3-ido-κ2 S 2,N)(4-phenyl-1,3-thia-zole-2-thiol-ato-κS 2)bis-muth.

OmicsDI is part of the ELIXIR infrastructure

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Bis(4-phenyl-2-sulfanyl-idene-2,3-di-hydro-1,3-thia-zol-3-ido-κ² S ²,N)(4-phenyl-1,3-thia-zole-2-thiol-ato-κS ²)bis-muth.