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Bis(1-dodecyl-4-aza-1-azoniabi-cyclo-[2.2.2]octane)tetra-iso-thio-cyanato-cobalt(II).

ABSTRACT: The title compound, [Co(C₁₈H₃₇N₂)₂(NCS)₄], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabi-cyclo-[2.2.2]octane (DABCO⁺) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octa-hedral coordination environment of the Co^II ion is completed through four N atoms of iso-thio-cyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C-H⋯N and C-H⋯S between the filamentous mol-ecules lead to the formation of layers parallel to (001).

SUBMITTER: Giltzau NO

PROVIDER: S-EPMC9462146 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Bis(1-dodecyl-4-aza-1-azoniabi-cyclo-[2.2.2]octane)tetra-iso-thio-cyanato-cobalt(II).

Giltzau Niels Ole NO Köckerling Martin M

IUCrData 20200128 Pt 1

The title compound, [Co(C18H37N2)2(NCS)4], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two trans-oriented 1-dodecyl-4-aza-1-azoniabi-cyclo-[2.2.2]octane (DABCO+) cations, which carry n-dodecyl chains at the non-coordinating N atoms. The distorted octa-hedral coordination environment of the CoII ion is completed through four N atoms o ...[more]

PMID: 36337714

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