Poly[[μ₄-3,4,8,10,11,13-hexa-hydro-1H,6H-bis-([1,4]di-thio-cino)[6,7-b:6',7'-e]pyrazine]di-μ-iodido-dicopper(I)]: a two-dimensional copper(I) coordination polymer.

ABSTRACT: The reaction of ligand 3,4,8,10,11,13-hexa-hydro-1H,6H-bis-([1,4]di-thio-cino)[6,7-b:6',7'-e]pyrazine (L) with CuI led to the formation of a two-dimensional coordination polymer, incorporating a [Cu₂I₂] motif. These units are linked via the four S atoms of the ligand to form the title two-dimensional coordination poly-mer, poly[[μ₄-3,4,8,10,11,13-hexa-hydro-1H,6H-bis-([1,4]di-thio-cino)[6,7-b:6',7'-e]pyrazine]di-μ-iodido-dicopper(I)], [Cu₂I₂(C₁₂H₁₆N₂S₄)] _n , (I). The asymmetric unit is composed of a ligand mol-ecule, two copper(I) atoms and two I^- ions. Both copper(I) atoms are fourfold S

SUBMITTER: Assoumatine T 

PROVIDER: S-EPMC9462211 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature