[1,2-Bis(diiso­propyl­phosphan­yl)ethane-κ2P,P′](2-fluoro-N-{[(2-fluoro­phen­yl)aza­nid­yl]carbon­yl}anilinido-κ2N,N′)nickel(II)

ABSTRACT: The NiII atom in the title compound shows a distorted square-planar P2N2 coordination set provided by two bidentate ligands. The mol­ecular structure of the title complex, [Ni(C13H8F2N2O)(C14H32P2)] or Ni(oFPU)(dippe), where oFPU is the dianion of bis­(2-fluoro­phen­yl)urea and dippe is 1,2-bis­(di-iso­propyl­phosphino)ethane, comprises an NiII atom with a distorted square-planar coordination environment (geometry index τ4 = 0.195). One of the fluoro­phenyl rings of the oFPU ligand is disordered over two sets of sites in an 0.832 (7):0.168 (7) ratio. The crystal structure displays C—H⋯O and C—H⋯F hydrogen-bonding inter­actions, leading to chains with R22(12) motifs extending parallel to [100]. The title compound might be of inter­est with respect to the production of urea and carbamate der

SUBMITTER: Flores-Alamo M 

PROVIDER: S-EPMC9462222 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature