Tetra­kis[μ2-5-nitro-2-(phenyl­sulfan­yl)benzoato-κ2O:O′]bis­[(aceto­nitrile-κN)copper(II)]

ABSTRACT: Pairs of bis-monodentate 5-nitro-2-phenyl­sulfanyl-benzoate ligands bridge two CuII atoms related by inversion symmetry. The square-pyramidal coordination geometry of each copper(II) atom is completed by an acetronitile ligand at the apex. The intra­molecular Cu⋯Cu distance in the dimer is 2.6478 (3) Å. The title compound, [Cu2(μ2-O2CC12H8NO2S)4(CH3CN)2], consists of a dinuclear and centrosymmetric complex based on two CuII atoms coordinated by four 5-nitro-2-phenyl­sulfanyl-benzoate anions and two aceto­nitrile ligands. Each benzoate anion acts as a bis-monodentate ligand while each aceto­nitrile acts as a monodentate ligand, leading to a square-pyramidal NO4 coordination environment for each CuII atom with the aceto­nitrile N atom at the apex. The intra­molecular Cu⋯Cu distance in the di

SUBMITTER: Xu D 

PROVIDER: S-EPMC9462229 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature