[2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ2P,P′]di­chlorido­platinum(II) acetonitrile trisolvate

ABSTRACT: The crystal structure of racemic di­chloro­[2,2′-bis­(di­phenyl­phosphino)-1,1′-binaphth­yl]platinum(II) has been determined at 150 K. The asymmetric unit consists of a single mol­ecule of the title compound co-crystallized with three aceto­nitrile solvent mol­ecules. The crystal structure (150 K) of the racemic title compound, [PtCl2(C44H32P2)]·3CH3CN, has been determined. The asymmetric unit comprises a single mol­ecule of the title compound co-crystallized with three aceto­nitrile solvent mol­ecules. Four mol­ecules are observed in the unit cell, with R and S enanti­omers present in a 2:2 ratio. Evidence of intra­molecular π-stacking is observed with no discernable inter­molecular inter­actions.

SUBMITTER: Braun J 

PROVIDER: S-EPMC9462241 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature