Di-μ-benzoato-di-μ-ethano-lato-tetra-kis-[μ₃-5-(hy-droxy-meth-yl)-2-methyl-4-(oxidometh-yl)pyridin-1-ium-3-olato]tetra-kis-[μ₃-5-(hy-droxy-meth-yl)-2-methyl-4-(oxidometh-yl)pyridin-3-olato]di-μ₃-oxido-hepta-manganese(II,III) ethanol octa-solvate.

ABSTRACT: Our work in the area of synthesis of polynuclear manganese complexes and their magnetic properties led to the synthesis and crystallization of the title compound, [Mn₇(C₈H₉NO₃)₄(C₈H₁₀NO₃)₄(C₂H₅O)₂(C₇H₅O₂)₂O₂]·8C₂H₅OH. Herein, we report the molecular and crystal structure of the title compound, which was synthesized by the reaction of Mn(C₆H₅COO)₂ with pyridoxine (PNH₂, C₈H₁₁NO₃) followed by the addition of tetra-methyl-ammonium hydroxide (TMAOH). The core of this centrosymmetric complex is a cage-like structu

SUBMITTER: Saha A 

PROVIDER: S-EPMC9462263 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature