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Di-μ₂-chlorido-bis-{chlorido-[2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-κ³ N ²,N ¹,N ⁶]nickel(II)}.

ABSTRACT: In the title compound, [Ni₂Cl₄(C₁₈H₁₂N₆)₂], the Ni^II ions are hexa-coordinated in a distorted octa-hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl^- anions in a meridional geometry. The two Ni^II ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni₂Cl₂ ring.

SUBMITTER: Ha K

PROVIDER: S-EPMC9462264 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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Di-μ2-chlorido-bis-{chlorido-[2,4,6-tris-(pyridin-2-yl)-1,3,5-triazine-κ3 N 2,N 1,N 6]nickel(II)}.

Ha Kwang K

IUCrData 20210129 Pt 1

In the title compound, [Ni2Cl4(C18H12N6)2], the NiII ions are hexa-coordinated in a distorted octa-hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl- anions in a meridional geometry. The two NiII ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is lo ...[more]

PMID: 36340472

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