Di-μ2-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ3N2,N1,N6]nickel(II)}

ABSTRACT: The NiII ions both show a distorted N3Cl3 octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand, two bridging Cl− ligands and a Cl− anion. In the title compound, [Ni2Cl4(C18H12N6)2], the NiII ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl− anions in a meridional geometry. The two NiII ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni2Cl2 ring.

SUBMITTER: Ha K 

PROVIDER: S-EPMC9462264 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature