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6-(3,4-Di-fluoro-phen-yl)-7,8,13,14-tetra-hydro-dibenzo[c,k]phenanthridine.

ABSTRACT: In the title compound, C₂₇H₁₉F₂N, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di-fluoro-benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C-H⋯N hydrogen bonds generate R ² ₂(12) loops and the dimers are further linked by weak C-H⋯F inter-actions to form [01] chains.

SUBMITTER: Fang Y

PROVIDER: S-EPMC9462275 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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6-(3,4-Di-fluoro-phen-yl)-7,8,13,14-tetra-hydro-dibenzo[c,k]phenanthridine.

Fang Yiwen Y Liu Bingbing B Jia Zhixiang Z

IUCrData 20200911 Pt 9

In the title compound, C27H19F2N, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di-fluoro-benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C-H⋯N hydrogen bonds generate R 2 2(12) loops and the dimers are further linked by weak C-H⋯F inter-actions to form [01] chains. ...[more]

PMID: 36338910

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