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Chlorido-(4'-chloro-2,2':6',2''-terpyridine-κ³ N,N',N'')(tri-fluoro-methane-sulfonato-κO)zinc(II) aceto-nitrile monosolvate.

ABSTRACT: In the title complex, [Zn(CF₃O₃S)Cl(C₁₅H₁₀ClN₃)]·CH₃CN, the zinc(II) core is fivefold coordinated by one chloride, one tri-fluoro-methane-sulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-chloro-terpyridine complexes because of the unusual planarity of the coordinated chloride, the short length of the Zn-N bond opposite to the chloride ligand [1.9572 (15) Å], and the presence of an elongated Zn-O bond [2.3911 (14) Å] in the coordinated tri-fluoro-methane-sulfonate ion. A molecule of acetonitrile is also found in the asymmetric unit of the title complex.

SUBMITTER: Adrian RA

PROVIDER: S-EPMC9462286 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Chlorido-(4'-chloro-2,2':6',2''-terpyridine-κ3 N,N',N'')(tri-fluoro-methane-sulfonato-κO)zinc(II) aceto-nitrile monosolvate.

Adrian Rafael A RA Arman Hadi D HD

IUCrData 20200930 Pt 9

In the title complex, [Zn(CF3O3S)Cl(C15H10ClN3)]·CH3CN, the zinc(II) core is fivefold coordinated by one chloride, one tri-fluoro-methane-sulfonate O atom and three terpyridine N atoms in a slightly distorted square-pyramidal geometry. The structure provides a distinct example amongst other zinc(II) 4-chloro-terpyridine complexes because of the unusual planarity of the coordinated chloride, the short length of the Zn-N bond opposi ...[more]

PMID: 36338906

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