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Bis-(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri-fluoro-butane-1,3-dionato-κ² O,O')nickel(II).

ABSTRACT: In the title compound, [NiFe₂(C₅H₅)(C₉H₅F₃O₂)₂(C₂H₆O)₂], the central Ni^II ion is observed in an octa-hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo-penta-diene rings. Coordinated ethanol mol-ecules are engaged in inter-molecular hydrogen bonds, and the crystal is further stabilized by weak C-H⋯F and C-H⋯π contacts.

SUBMITTER: Su W

PROVIDER: S-EPMC9462358 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature

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Bis-(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri-fluoro-butane-1,3-dionato-κ2 O,O')nickel(II).

Su Wenqing W Fu Tianyue T Xu Zhongwei Z

IUCrData 20210713 Pt 7

In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octa-hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo-penta-diene rings. Coordinated ethanol mol-ecules are engag ...[more]

PMID: 36340661

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