Exclusive Solution Discharge in Li-O₂ Batteries?

ABSTRACT: Capacity, rate performance, and cycle life of aprotic Li-O₂ batteries critically depend on reversible electrodeposition of Li₂O₂. Current understanding states surface-adsorbed versus solvated LiO₂ controls Li₂O₂ growth as surface film or as large particles. Herein, we show that Li₂O₂ forms across a wide range of electrolytes, carbons, and current densities as particles via solution-mediated LiO₂ disproportionation, bringing into question the prevalence of any surface growth under practical conditions. We describe a unified O₂ reduction mechanism, which can explain all found capacity relations and Li₂O₂ morphologies with exclusive solution discharge. Determinin

SUBMITTER: Prehal C 

PROVIDER: S-EPMC9469202 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature