Ternary metal oxide nanocomposite for room temperature H₂S and SO₂ gas removal in wet conditions.

ABSTRACT: A ternary Mn-Zn-Fe oxide nanocomposite was fabricated by a one-step coprecipitation method for the remotion of H₂S and SO₂ gases at room temperature. The nanocomposite has ZnO, MnO₂, and ferrites with a surface area of 21.03 m² g^-1. The adsorbent was effective in mineralizing acidic sulfurous gases better in wet conditions. The material exhibited a maximum H₂S and SO₂ removal capacity of 1.31 and 0.49 mmol g^-1, respectively, in the optimized experimental conditions. The spectroscopic analyses confirmed the formation of sulfide, sulfur, and sulfite as the mineralized products of H₂S. Additionally, the nanocomposite could convert SO₂ to sulfate as the sole oxidation by-product. The oxidation of these toxic gases was driven by the dissolution and dissociation of gas molecules in surface adsorbed water, followed by the redox behaviour of transition metal ions in the presence of molecular oxygen and water. Thus, the study presented a potential nanocomposite adsorbent for deep desulfurization applications.

SUBMITTER: Gupta NK 

PROVIDER: S-EPMC9470665 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature