Accelerating the water splitting kinetics of CoP microcubes anchored on a graphene electrocatalyst by Mn incorporation.

ABSTRACT: CoP is considered as an efficient electrocatalyst for the hydrogen evolution reaction (HER) in acidic electrolytes but its performance in alkaline solutions is generally poor because of its slow reaction kinetics, which further limits its application in overall water splitting. Herein, we demonstrate a strategy to greatly accelerate its HER and OER kinetics in alkaline solutions through Mn incorporation. Ternary Mn _x Co_1-x P microcubes with a tunable Mn/Co ratio strongly anchored on rGO were synthesized using Prussian blue analogues as precursors. The synergy between the high activity of Mn _x Co_1-x P microcubes and the good conductivity of rGO leads to the superior performance of the hybrid toward water splitting in 1

SUBMITTER: Xu X 

PROVIDER: S-EPMC9473208 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature