Noble metal supported hexagonal boron nitride for the oxygen reduction reaction: a DFT study.

ABSTRACT: Discovering active, stable and cost-effective catalysts for the oxygen reduction reaction (ORR) is of utmost interest for commercialization of fuel cells. Scarce and expensive noble metals such as Pt and Pd are the state-of-the-art active ORR catalysts but suffer from low stability against CO poisoning. Hexagonal boron nitride (h-BN) is a particularly attractive material due to its low cost and stability; however, it suffers from intrinsic low activity toward the ORR in the pristine form as a result of its inherently low conductivity with a large band gap of ∼5.5 electron volts. During the past few years, several strategies such as using metal supports, metal doping and atomic vacancies have been reported to significantly increase the conductivity, thereby promoting the ORR activity. Herei

SUBMITTER: Back S 

PROVIDER: S-EPMC9473273 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature