Lewis acid-catalyzed Pudovik reaction-phospha-Brook rearrangement sequence to access phosphoric esters.

ABSTRACT: Herein, we report a Lewis acid-catalyzed Pudovik reaction-phospha-Brook rearrangement sequence between diarylphosphonates or -phosphinates and α-pyridinealdehydes to access valuable phosphoric ester compounds. This transformation provides an extended substrate scope that is complementary to similar previously reported base-catalyzed transformations.

SUBMITTER: Yang J 

PROVIDER: S-EPMC9475178 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature