Synthesis and Corrosion Inhibition Performance of Mannich Bases on Mild Steel in Lactic Acid Media.

ABSTRACT: Heterocyclic Mannich bases, N-(3-oxo-3-phenylpro-pyl)thiazol-2-aminium chloride (DTZA) and N-(3-oxo-3-phenylpropyl)-1H-pyrazol-3-aminium chloride (DPZA), were developed for the corrosion inhibition of N80 steel in a 15 wt % lactic acid solution. Weight loss measurements, electrochemical techniques, surface characterization, and theoretical calculations were combined to investigate their anticorrosion performance and mechanism. The results showed that DTZA exhibited a satisfactory inhibitor efficiency of 97.56% with a dosage of 0.15% at 363 K, while DPZA achieved only 58.3% under the same conditions. Adsorptions of both inhibitors on the metal surface followed the Langmuir model with physical and chemical adsorptions. Based on X-ray photoelectronic spectroscopy (XPS) an

SUBMITTER: Zhang X 

PROVIDER: S-EPMC9476531 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature