Flexible and Conductive Polymer Threads for Efficient Fiber-Shaped Supercapacitors via Vapor Copolymerization.

ABSTRACT: Flexible fiber electrodes are critical for high-performance fiber and wearable electronics. In this work, we presented a highly conductive all-polymer fiber electrode by vapor copolymerization of 2,5-dibromo-3,4-vinyldioxythiophene (DBEDOT) and 2,5-diiodo-3,4-vinyldioxythiophene (DIEDOT) monomers on commonly used polyester threads (PETs) at a temperature as low as 80 °C. The poly(3,4-ethylenedioxythiophene) (PEDOT)-coated PET threads maintain excellent flexibility and show conductivity of 7.93 S cm^-1, nearly four times higher than that reported previously via homopolymerization of DBEDOT monomer. A MnO₂ active layer was embedded into the PEDOT double layers, and the flexible fiber composite electrode showed a high linear specific capacitance of 157 mF cm^-1

SUBMITTER: Hu J 

PROVIDER: S-EPMC9476533 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature