A library of polytypic copper-based quaternary sulfide nanocrystals enables efficient solar-to-hydrogen conversion.

ABSTRACT: Designing polytypic homojunction is an efficient way to regulate photogenerated electrons and holes, thereafter bringing desired physical and chemical properties and being attractive photocatalysts for solar-to-hydrogen conversion. However, the high-yield and controllable synthesis of well-defined polytypes especially for multinary chalcogenide - the fundamental factor favoring highly efficient solar-to-hydrogen conversion - has yet to be achieved. Here, we report a general colloidal method to construct a library of polytypic copper-based quaternary sulfide nanocrystals, including Cu₂ZnSnS₄, Cu₂CdSnS₄, Cu₂CoSnS₄, Cu₂MnSnS₄, Cu₂FeSnS₄, Cu₃InSnS₅ and Cu₃

SUBMITTER: Wu L 

PROVIDER: S-EPMC9477825 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature