Role of chemisorbing species in growth at liquid metal-electrolyte interfaces revealed by in situ X-ray scattering.

ABSTRACT: Liquid-liquid interfaces offer intriguing possibilities for nanomaterials growth. Here, fundamental interface-related mechanisms that control the growth behavior in these systems are studied for Pb halide formation at the interface between NaX + PbX₂ (X = F, Cl, Br) and liquid Hg electrodes using in situ X-ray scattering and complementary electrochemical and microscopy measurements. These studies reveal a decisive role of the halide species in nucleation and growth of these compounds. In Cl- and Br-containing solution, deposition starts by rapid formation of well-defined ultrathin (∼7 Å) precursor adlayers, which provide a structural template for the subsequent quasi-epitaxial growth of c-axis oriented Pb(OH)X bulk crystals. In contrast, growth in F-containing solution proceeds

SUBMITTER: Sartori A 

PROVIDER: S-EPMC9477831 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature