Sweet Spot of Intermolecular Coupling in Crystalline Rubrene: Intermolecular Separation to Minimize Singlet Fission and Retain Triplet-Triplet Annihilation.

ABSTRACT: Singlet fission is detrimental to NIR-to-vis photon upconversion in the solid rubrene (Rub) films, as it diminishes photoluminescence efficiency. Previous studies have shown that thermally activated triplet energy transport drives singlet fission with nearly 100% efficiency in closely packed Rub crystals. Here, we examine triplet separation and recombination as a function of intermolecular distance in the crystalline films of Rub and the t-butyl substituted rubrene (tBRub) derivative. The increased intermolecular distance and altered molecular packing in tBRub films cause suppressed singlet dissociation into free triplets due to slower triplet energy transport. It was found that the formation of correlated triplet pairs ¹(TT) and partial triplet separation <

SUBMITTER: Baronas P 

PROVIDER: S-EPMC9484276 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature