Vitrimers trigger covalent bonded bio-silica fused composite materials for recycling, reshaping, and self-healing applications.

ABSTRACT: In this work, a recycling, reshaping, and self-healing strategy was followed for polybenzoxazine through S-S bond cleavage reformation in vitrimers, and the supramolecular interactions are described. The E-ap benzoxazine monomer was synthesized through the Mannich condensation reaction using a renewable eugenol, 3-amino-1-propanol and paraformaldehyde. Furthermore, the E-3ap monomer was reinforced with various weight percentages (5, 10, and 15 wt%) of the thiol-ene group. Various weight percentages of functionalized bio-silica (BS) were also copolymerized with E-3ap (10%-SH) to increase the thermal stability. The structure of the monomers was confirmed by NMR and FT-IR analysis and the thermal properties of the cured materials were analyzed by DSC and TGA. Tensile test was used to study th

SUBMITTER: Sriharshitha S 

PROVIDER: S-EPMC9490535 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature