2-D Molecular Alloy Ru-M (M = Cu, Ag, and Au) Carbonyl Clusters: Synthesis, Molecular Structure, Catalysis, and Computational Studies.

ABSTRACT: The reactions of [HRu₃(CO)₁₁]^- (1) with M(I) (M = Cu, Ag, and Au) compounds such as [Cu(CH₃CN)₄][BF₄], AgNO₃, and Au(Et₂S)Cl afford the 2-D molecular alloy clusters [CuRu₆(CO)₂₂]^- (2), [AgRu₆(CO)₂₂]^- (3), and [AuRu₅(CO)₁₉]^- (4), respectively. The reactions of 2-4 with PPh₃ result in mixtures of products, among which [Cu₂Ru₈(CO)₂₆]^2- (5), Ru₄(CO)₁₂(CuPPh₃)₄ (6), Ru₄(CO)₁₂(AgPPh₃)₄ (7), Ru(CO)₃(PPh

SUBMITTER: Cesari C 

PROVIDER: S-EPMC9490753 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature