Carbene Complexes of Neptunium.

ABSTRACT: Since the advent of organotransuranium chemistry six decades ago, structurally verified complexes remain restricted to π-bonded carbocycle and σ-bonded hydrocarbyl derivatives. Thus, transuranium-carbon multiple or dative bonds are yet to be reported. Here, utilizing diphosphoniomethanide precursors we report the synthesis and characterization of transuranium-carbene derivatives, namely, diphosphonio-alkylidene- and N-heterocyclic carbene-neptunium(III) complexes that exhibit polarized-covalent σ²π² multiple and dative σ² single transuranium-carbon bond interactions, respectively. The reaction of [Np^IIII₃(THF)₄] with [Rb(BIPM^TMSH)] (BIPM^TMSH = {HC(PPh₂NSiMe₃)₂}

SUBMITTER: Goodwin CAP 

PROVIDER: S-EPMC9490846 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature