Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures.

ABSTRACT: Alkynyl ligands stabilize dimers [Ir(μ-X)(3b)₂]₂ with a cis disposition of the heterocycles of the 3b ligands, in contrast to chloride. Thus, the complexes of this class─cis-[Ir(μ₂-η²-C≡CPh){κ²-C,N-(C₆H₄-Isoqui)}₂]₂ (Isoqui = isoquinoline) and cis-[Ir(μ₂-η²-C≡CR){κ²-C,N-(MeC₆H₃-py)}₂]₂ (R = Ph, ^tBu)─have been prepared in high yields, starting from the dihydroxo-bridged dimers trans-[Ir(μ-OH){κ²-C,N-(C₆H₄-Isoqui)}₂]₂ and trans-[Ir(μ-OH){κ²-C,N-(MeC

SUBMITTER: Adamovich V 

PROVIDER: S-EPMC9490848 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature