Elastic Buffering Layer on CuS Enabling High-Rate and Long-Life Sodium-Ion Storage.

ABSTRACT: The latest view suggests the inactive core, surface pulverization, and polysulfide shuttling effect of metal sulfides are responsible for their low capacity and poor cycling performance in sodium-ion batteries (SIBs). Whereas overcoming the above problems based on conventional nanoengineering is not efficient enough. In this work, erythrocyte-like CuS microspheres with an elastic buffering layer of ultrathin polyaniline (PANI) were synthesized through one-step self-assembly growth, followed by in situ polymerization of aniline. When CuS@PANI is used as anode electrode in SIBs, it delivers high capacity, ultrahigh rate capability (500 mAh g^-1 at 0.1 A g^-1, and 214.5 mAh g^-1 at 40 A g^-1), and superior cycling life of over 7500 cycles at 20 A g

SUBMITTER: Xiao Y 

PROVIDER: S-EPMC9508307 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature