Photophysical Properties and DNA Binding of Two Intercalating Osmium Polypyridyl Complexes Showing Light-Switch Effects.

ABSTRACT: The synthesis and photophysical characterization of two osmium(II) polypyridyl complexes, [Os(TAP)₂dppz]²⁺ (1) and [Os(TAP)₂dppp2]²⁺ (2) containing dppz (dipyrido[3,2-a:2',3'-c]phenazine) and dppp2 (pyrido[2',3':5,6]pyrazino[2,3-f][1,10]phenanthroline) intercalating ligands and TAP (1,4,5,8-tetraazaphenanthrene) ancillary ligands, are reported. The complexes exhibit complex electrochemistry with five distinct reductive redox couples, the first of which is assigned to a TAP-based process. The complexes emit in the near-IR (1 at 761 nm and 2 at 740 nm) with lifetimes of >35 ns with a low quantum yield of luminescence in aqueous solution (∼0.25%). The Δ and Λ enantiomers of 1 and 2 are f

SUBMITTER: Stitch M 

PROVIDER: S-EPMC9516684 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature