Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N-O Bond Cleavage Reactions.

ABSTRACT: The novel nitrosyl-bridged complex [W₂Cp₂(μ-P^tBu₂)(μ-κ:η-NO)(CO)(NO)](BAr₄) [Ar = 3,5-C₆H₃(CF₃)₂] was prepared in a multistep procedure starting from the hydride [W₂Cp₂(μ-H)(μ-P^tBu₂)(CO)₄] and involving the new complexes [W₂Cp₂(μ-P^tBu₂)(CO)₄](BF₄), [W₂Cp₂(μ-P^tBu₂)(CO)₂(NO)₂](BAr₄), and [W₂(μ-κ:η⁵-C₅H₄)Cp(μ-P^tBu₂)(CO)(NO)₂] as intermediates, which follow from reactions with HBF₄

SUBMITTER: Alvarez MA 

PROVIDER: S-EPMC9516685 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature