Confinement effects facilitate low-concentration carbon dioxide capture with zeolites.

ABSTRACT: Engineered systems designed to remove CO₂ from the atmosphere need better adsorbents. Here, we report on zeolite-based adsorbents for the capture of low-concentration CO₂. Synthetic zeolites with the mordenite (MOR)-type framework topology physisorb CO₂ from low concentrations with fast kinetics, low heat of adsorption, and high capacity. The MOR-type zeolites can have a CO₂ capacity of up to 1.15 and 1.05 mmol/g for adsorption from 400 ppm CO₂ at 30 °C, measured by volumetric and gravimetric methods, respectively. A structure-performance study demonstrates that Na⁺ cations in the O33 site located in the side-pocket of the MOR-type framework, that is accessed through a ring of eight tetrahedral atoms (either Si⁴⁺

SUBMITTER: Fu D 

PROVIDER: S-EPMC9522334 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature