The missing base molecules in atmospheric acid-base nucleation.

ABSTRACT: Transformation of low-volatility gaseous precursors to new particles affects aerosol number concentration, cloud formation and hence the climate. The clustering of acid and base molecules is a major mechanism driving fast nucleation and initial growth of new particles in the atmosphere. However, the acid-base cluster composition, measured using state-of-the-art mass spectrometers, cannot explain the measured high formation rate of new particles. Here we present strong evidence for the existence of base molecules such as amines in the smallest atmospheric sulfuric acid clusters prior to their detection by mass spectrometers. We demonstrate that forming (H₂SO₄)₁(amine)₁ is the rate-limiting step in atmospheric H₂SO₄-amine nucl

SUBMITTER: Cai R 

PROVIDER: S-EPMC9522409 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature