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Local Shearing Force Measurement during Frictional Sliding Using Fluorogenic Mechanophores.


ABSTRACT: When two macroscopic objects touch, the real contact typically consists of multiple surface asperities that are deformed under the pressure that holds the objects together. Application of a shear force makes the objects slide along each other, breaking the initial contacts. To investigate how the microscopic shear force at the asperity level evolves during the transition from static to dynamic friction, we apply a fluorogenic mechanophore to visualize and quantify the local interfacial shear force. When a contact is broken, the shear force is released and the molecules return to their dark state, allowing us to dynamically observe the evolution of the shear force at the sliding contacts. We find that the macroscopic coefficient of friction describes the microscopic friction well, and that slip propagates from the edge toward the center of the macroscopic contact area before sliding occurs. This allows for a local understanding of how surfaces start to slide.

SUBMITTER: Hsu CC 

PROVIDER: S-EPMC9531245 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature

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Local Shearing Force Measurement during Frictional Sliding Using Fluorogenic Mechanophores.

Hsu Chao-Chun CC   Hsia Feng-Chun FC   Weber Bart B   de Rooij Matthijn B MB   Bonn Daniel D   Brouwer Albert M AM  

The journal of physical chemistry letters 20220916 38


When two macroscopic objects touch, the real contact typically consists of multiple surface asperities that are deformed under the pressure that holds the objects together. Application of a shear force makes the objects slide along each other, breaking the initial contacts. To investigate how the microscopic shear force at the asperity level evolves during the transition from static to dynamic friction, we apply a fluorogenic mechanophore to visualize and quantify the local interfacial shear for  ...[more]

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