Using temperature dependent fluorescence to evaluate singlet fission pathways in tetracene single crystals.

ABSTRACT: The temperature-dependent fluorescence spectrum, decay rate, and spin quantum beats are examined in single tetracene crystals to gain insight into the mechanism of singlet fission. Over the temperature range of 250 K-500 K, the vibronic lineshape of the emission indicates that the singlet exciton becomes localized at 400 K. The fission process is insensitive to this localization and exhibits Arrhenius behavior with an activation energy of 550 ± 50 cm^-1. The damping rate of the triplet pair spin quantum beats in the delayed fluorescence also exhibits an Arrhenius temperature dependence with an activation energy of 165 ± 70 cm^-1. All the data for T > 250 K are consistent with direct production of a spatially separated ¹(T⋯T) state via a thermally activated pr

SUBMITTER: Cruz CD 

PROVIDER: S-EPMC9533257 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature