[3+2] click chemistry approach to tetrazine containing polymers.

ABSTRACT: We report a [3+2] cycloaddition using 3,6-bis-propargyloxy-1,2,4,5-tetrazine and azides to synthesize energetic polymers containing 1,2,4,5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1,2,4,5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach.

SUBMITTER: Chavez DE 

PROVIDER: S-EPMC9535468 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature