Syntheses and crystal structures of the ethanol, acetonitrile and diethyl ether Werner clathrates bis-(iso-thio-cyanato-κN)tetra-kis-(3-methyl-pyridine-κN)nickel(II).

ABSTRACT: The reaction of nickel(II)thio-cyanate with 3-methyl-pyridine (3-picoline; C₆H₇N) in different solvents leads to the formation of crystals of bis-(iso-thio-cyanato-κN)tetra-kis-(3-methyl-pyridine-κN)nickel(II) as the ethanol disolvate, [Ni(NCS)₂(C₆H₇N)₄]·2C₂H₅OH (1), the acetonitrile disolvate, [Ni(NCS)₂(C₆H₇N)₄]·2CH₃CN (2), and the diethyl ether monosolvate, [Ni(NCS)₂(C₆H₇N)₄]·C₄H₁₀O (3). The crystal structures of these compounds consist of Ni^II cations coordinated by two N-bonded thio-cyanate anions and four 3-methyl-pyridine ligands to

SUBMITTER: Krebs C 

PROVIDER: S-EPMC9535821 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature