Critical Role of Iodous Acid in Neutral Iodine Oxoacid Nucleation.

ABSTRACT: Nucleation of neutral iodine particles has recently been found to involve both iodic acid (HIO₃) and iodous acid (HIO₂). However, the precise role of HIO₂ in iodine oxoacid nucleation remains unclear. Herein, we probe such a role by investigating the cluster formation mechanisms and kinetics of (HIO₃)_m(HIO₂)_n (m = 0-4, n = 0-4) clusters with quantum chemical calculations and atmospheric cluster dynamics modeling. When compared with HIO₃, we find that HIO₂ binds more strongly with HIO₃ and also more strongly with HIO₂. After accounting for ambient vapor concentrations, the fastest nucleation rate is predicted for mixed HIO₃-HIO₂

SUBMITTER: Zhang R 

PROVIDER: S-EPMC9536010 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature