Two-Dimensional Crystals as a Buffer Layer for High Work Function Applications: The Case of Monolayer MoO₃.

ABSTRACT: We propose that the crystallinity of two-dimensional (2D) materials is a crucial factor for achieving highly effective work function (WF) modification. A crystalline 2D MoO₃ monolayer enhances substrate WF up to 6.4 eV for thicknesses as low as 0.7 nm. Such a high WF makes 2D MoO₃ a great candidate for tuning properties of anode materials and for the future design of organic electronic devices, where accurate evaluation of the WF is crucial. We provide a detailed investigation of WF of 2D α-MoO₃ directly grown on highly ordered pyrolytic graphite, by means of Kelvin probe force microscopy (KPFM) and ultraviolet photoemission spectroscopy (UPS). This study underlines the importance of a controlled environment and the resulting crystallinity to achieve high W

SUBMITTER: Kowalczyk DA 

PROVIDER: S-EPMC9542700 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature