Metal-Catalyzed, Photo-Assisted Selective Transformation of Tertiary Alkylbenzenes and Polystyrenes into Carbonyl Compounds.

ABSTRACT: Every year, thousands of tons of polystyrene are produced and discarded, filling landfills and polluting the marine environment. Although several degradation alternatives have been proposed, the need for an effective procedure for the chemical recycling of polystyrene still remains. Here, a vanadium-catalyzed reaction, assisted by visible light, promoted the direct, selective conversion of tertiary alkylbenzenes into acetophenone and other ketone derivatives. Likewise, standard polystyrene samples as well as polystyrenes from insulation and packaging waste could be chemically recycled into acetophenone in a scalable way regardless of their molecular weight, polydispersity, or form. Preliminary mechanistic investigations revealed the participation of singlet oxygen, superoxide, and hydroxyl

SUBMITTER: Urgoitia G 

PROVIDER: S-EPMC9544855 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature