Robust and Self-Cleaning Electrochemical Production of Periodate.

ABSTRACT: Periodate, a platform oxidizer, can be electrochemically recycled in a self-cleaning process. Electrosynthesis of periodate is well established at boron-doped diamond (BDD) anodes. However, recovered iodate and other iodo species for recycling can contain traces of organic impurities from previous applications. For the first time, it was shown that the organic impurities do not hamper the electrochemical re-oxidation of used periodate. In a hydroxyl-mediated environment, the organic compounds form CO₂ and H₂ O during the degradation process. This process is often referred to as "cold combustion" and provides orthogonal conditions to periodate synthesis. To demonstrate the strategy, different dyes, pharmaceutically active ingredients, and iodine compounds were added as

SUBMITTER: Kisukuri CM 

PROVIDER: S-EPMC9546426 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature