Step-by-step desolvation enables high-rate and ultra-stable sodium storage in hard carbon anodes.

ABSTRACT: Hard carbon is regarded as the most promising anode material for sodium-ion (Na-ion) batteries, owing to its advantages of high abundance, low cost, and low operating potential. However, the rate capability and cycle life span of hard carbon anodes are far from satisfactory, severely hindering its industrial applications. Here, we demonstrate that the desolvation process defines the Na-ion diffusion kinetics and the formation of a solid electrolyte interface (SEI). The 3A zeolite molecular sieve film on the hard carbon is proposed to develop a step-by-step desolvation pathway that effectively reduces the high activation energy of the direct desolvation process. Moreover, step-by-step desolvation yields a thin and inorganic-dominated SEI with a lower activation energy for Na⁺ tra

SUBMITTER: Lu Z 

PROVIDER: S-EPMC9546550 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature